Magnetic properties of linear trimers in fluoride analogs of tetragonal tungsten bronze |
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| Authors: | Yaw-Shun Hong |
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| Institution: | Department of Chemistry and Biochemistry, University of Mississippi, University, MS 38677, USA |
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| Abstract: | The compounds KZnTiF6, KZnVF6, KVScF6, KCrScF6, and KMnScF6 are fluoride analogs of Tetragonal Tungsten Bronze. M2+-M3+ ionic ordering in these fluorides provided systems which contained linear trinuclear complexes of their respective paramagnetic ions. Magnetic coupling within these linear trimers occurred below 100 K in each of the five systems. Derived magnetic susceptibility equations were fitted to observed magnetic susceptibilities for each of the possible spin systems: KZnTiF6 (S=1/2), J/k=−114 K; KZnVF6 (S=1), J/k=−39 K; KVScF6 (S=3/2), J/k=−16 K; KCrScF6 (S=2), J/k=−4 K; and KMnScF6 (S=5/2), J/k=−7.5 K. |
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| Keywords: | Linear trinuclear complexes Linear trimers Tetragonal tungsten bronze Ionic ordering Magnetic coupling Magnetic susceptibility |
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