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Carbon nanotube—chalcogenide glass composite
Authors:Stepan Stehlik  Tomas Kohoutek  Miloslav Frumar  Toru Hara  Kazuyuki Ueda
Institution:a Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Legion's sq. 565, 53210 Pardubice, Czech Republic
b Joint Laboratory of Solid State Chemistry of the Institute of Macromolecular Chemistry Academy of Sciences, University of Pardubice, Studentska 84, 52310 Pardubice, Czech Republic
c High-Voltage Electron Microscopy Station, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan
d Nano High Tech Research Center, Toyota Technological Institute, Nagoya 468-8511, Japan
e International Center for Materials Nanoarchitectonics and Biomaterials Center, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan
Abstract:This article describes the preparation of multi-walled carbon nanotube—chalcogenide glass composite by direct synthesis and the melt-quenching method. The carbon nanotubes—chalcogenide glass composite was characterized by high-resolution transmission electron microscopy (HRTEM), TEM/energy-dispersive X-ray spectroscopy, low energy electron excited X-ray spectroscopy, Raman spectroscopy, spectroscopic ellipsometry, microhardness, and impedance spectroscopy. CNTs-AgAsS2 glass composite possess highly increased ionic conductivity, from σ25 °C=4.38±0.0438×10−6 to σ25 °C=6.57±0.0657×10−6 S cm−1 and decreased refractive index from n=2.652 to 2.631 at the wavelength λ=1.55 μm.
Keywords:Carbon nanotubes  Chalcogenide glasses  Ion conductivity  Composites
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