| Crystal Structure and Spectroscopic and Coordination Properties of Bis（4-fluorobenzohydroxamato）dimethyltin（Ⅳ） |
| |
| 引用本文： | SHANG Xian-Meia MENG Xiang-Gaob② a.Crystal Structure and Spectroscopic and Coordination Properties of Bis（4-fluorobenzohydroxamato）dimethyltin（Ⅳ）[J].结构化学,2008,27(6):683-686. |
| |
| 作者姓名： | SHANG Xian-Meia MENG Xiang-Gaob② a |
| |
| 作者单位： | School of Pharmaceutical Science of Tongji Medical College Huazhong University of Science and Technology，Department of Chemistry，Central China Normal University，Wuhan 430030，China，Wuhan 430079，China |
| |
| 基金项目： | Project supported by the Health Commission of Hubei Province of China (No. 2007JX3B02) |
| |
| 摘 要： | An organotin（Ⅳ） complex （CH3）2Sn（4-FC6H4CONHO）2] has been synthesized and characterized by elemental analysis, IR, ^1H NMR and X-ray single-crystal diffraction techni- ques. The crystal belongs to the orthorhombic system, space group Pbca with a = 9.7565（13）, b = 17.664（2）, c = 20.784（3）A, Z = 8, V = 3581.9（8）A^3 Dc = 1.695 g/cm^3,μ（MoKa） = 1.469 mm^-1, F（000） = 1808, R = 0.0321 and wR = 0.0838. In the molecular structure of the title complex, the tin atoms are five-coordinated in a trigonal bipyramidal geometry, and the special coordination properties of dimethyltin（Ⅳ） with hydroxamate-type ligands are also discussed.
|
| 关 键 词： | 有机锡配合物 配位特征 元素分析 合成 晶体结构 |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
