Hydrochlorinated derivatives of syndiotactic 1,2-polybutadiene |
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| Authors: | A B Glazyrin M I Abdullin R R Muslukhov V A Kraikin |
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| Institution: | 1.Bashkir State University,Ufa,Bashkortostan, Russia;2.Institute of Organic Chemistry, Ufa Research Center,Russian Academy of Sciences,Ufa,Bashkortostan, Russia |
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| Abstract: | Chlorine-containing polymeric products with a degree of functionalization of up to 70% are synthesized through the hydrochlorination
of syndiotactic 1,2-polybutadiene via carbon-carbon double bonds. The introduction of chlorine atoms into polydiene units
causes substantial changes in the viscosity of polymer solutions, the flowability of the polymer melt, the glass-transition
and flow temperatures, and the thermal stability of polymers. The hydrochlorinated derivatives of syndiotactic 1,2-polybutadiene
demonstrate good adhesion with respect to steel and can be used in adhesive compositions. |
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