Effect of CNT incorporation on PAN/PPy nanofibers synthesized by electrospinning method |
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Authors: | Atike NCE YARDIMCI Metin TANOLU Selahattin YILMAZ Yusuf SELAMET |
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Institution: | 1. Department of Material Science and Engineering, İzmir Institute of Technology, İzmir, Turkey ; 2. Technology Transfer Office, Uşak University, Uşak, Turkey ; 3. Department of Mechanical Engineering, İzmir Institute of Technology, İzmir, Turkey ; 4. Department of Chemical Engineering, İzmir Institute of Technology, İzmir, Turkey ; 5. Department of Physics, İzmir Institute of Technology, İzmir, Turkey |
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Abstract: | In this study, carbon nanotubes (CNTs) added polyacrylonitrile/polypyrrole (PAN/PPy) electrospun nanofibers were produced. Average diameters of the nanofibers were measured as 268 and 153 nm for 10 and 25 wt% of PPy contents, respectively. A relatively higher strain to failure values (23.3%) were observed for the low PPy content. When as-grown CNTs (1 and 4 wt%) were added into the PAN/PPy blends, disordered nanofibers were observed to form within the microstructure. To improve the interfacial properties of CNTs/PAN/PPy composites, CNTs were functionalized with H2SO4/HNO3/HCl solution. The functionalized CNTs were well dispersed within the nanofibers and aligned along the direction of nanofibers. Therefore, beads formation on nanofibers decreased. The impedance of the nanofibers was found to decrease with the PPy content and CNT addition. These nanofibers had a great potential to be used as an electrochemical actuator or a tissue engineering scaffold. |
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Keywords: | Carbon nanotube electrospinning polyacrylonitrile/polypyrrole nanofibers |
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