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Pyranosidic homologation: Part I: Extending the carbohydrate template C6 and C4 |
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| Authors: | Bruce F Molino Leon Magdzinski Bert Fraser-Reid |
| Abstract: | The aldehyde ( ) reacts with ylid ( ) to give ( ) as 4:1 Z/E mixture which, upon methanolysis under catalysis by pyridinium -toluenesulfonate (PPTS), affords the bispyranoside ( ) as single anomer. |
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