| Highly Effective Propylene Epoxidation with Hydrogen—Oxygen Mixture over Ag／TS—1 Catalysts |
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| 作者姓名： | WANGRuipu HAOJingquan GUOXinwen WANGXiangsheng |
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| 作者单位： | StateKeyLaboratoryofFineChemicals,DalianUniversityofTechnology,Dalian116012,Liaoning,China |
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| 基金项目： | SupportedbytheChineseMinistryofEducationfortheScientificResearch ( 99150)andtheNationalKeyBasicResearchProjectofChina (G2 0 0 0 0 480 0 9) |
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| 摘 要： | Propyleneoxide (PO)isoneofthemostim portantchemicalfeedstocksforproducingpolyetherpolyolpolymerssuchaspolyurethane .Commercial ly ,POismanufacturedbyeitherchlorohydrinorco production (Halcon)route.Thechlorohydrinroutegenerateschlorinatedby products,mainlydichloro propaneandCaCl2 .Theco productionrouteiscapi talintensiveanditseconomicsislinkedtotheeco nomicfortunesoftheby products,namelystyreneortert butylalcohol. Theinventionoftitaniumsilicate 1 (TS 1 )openedanewrouteforthesynthesisofP…
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| 关 键 词： | 氢氧混合体系 Ag／TS－l催化剂 丙烯 环氧化反应 钛硅分子筛 负载型银催化剂 |
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