The synthesis and X-ray structure of the first cobalt carbonyl-NHC dimer. implications for the use of NHCs in hydroformylation catalysis |
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| Authors: | van Rensburg Hendrik Tooze Robert P Foster Douglas F Slawin Alexandra M Z |
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| Affiliation: | Sasol Technology (UK), Purdie Building, North Haugh, St. Andrews, Fife, UK, KY16 9ST. hendrik.vanrensburg@sasol.com |
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| Abstract: | The synthesis, X-ray structure, and catalytic properties of the first cobalt carbonyl dimer supported by a N-heterocyclic carbene ligand Co(2)(CO)(6)(IMes)(2) [IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene] is reported. |
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