| 三维配位聚合物[C4H12N2]3[PMo12O40]的合成、结构及其电化学性质 |
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| 引用本文： | 齐艳娟,苑晓冬,田 利. 三维配位聚合物[C4H12N2]3[PMo12O40]的合成、结构及其电化学性质[J]. 无机化学学报, 2009, 25(6): 1110-1114 |
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| 作者姓名： | 齐艳娟 苑晓冬 田 利 |
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| 作者单位： | 长春师范学院化学学院,长春,130032 |
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| 基金项目： | 吉林省科技发展计划项目 |
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| 摘 要： |
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| 关 键 词： | 水热合成 哌嗪 电化学性质 |
Synthesis, Structure and Electrochemical Properties of Three-Dimensional Complex [C4H12N2]3[PMo12O40] |
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| QI Yan-Juan,YUAN Xiao-Dong and TIAN Li. Synthesis, Structure and Electrochemical Properties of Three-Dimensional Complex [C4H12N2]3[PMo12O40][J]. Chinese Journal of Inorganic Chemistry, 2009, 25(6): 1110-1114 |
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| Authors: | QI Yan-Juan YUAN Xiao-Dong TIAN Li |
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| Affiliation: | Department of Chemistry of Changchun Normal University, Changchun 130032,Department of Chemistry of Changchun Normal University, Changchun 130032 and Department of Chemistry of Changchun Normal University, Changchun 130032 |
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| Abstract: | The title compound [C4H12N2] 3 [PMo12O40] was synthesized from the hydrothermal reaction and charac-terized by IR, elemental analysis and X-ray signal crystal structural analysis. The crystal of the title complex belongs to trigonal space group R3c with a=1.788 62 nm, c=2.354 3 nm, and V=6.522 62 nm3, Z=6, R1=0.038 4, wR2=0.102 0. The compound consisted of piperazine and PMo12O403-, and the structure is extended to three dimensional framework owing to the hydrogen bond between the O atoms and N atoms. The bulk-modified carbon paste electrode (APM-CPE) using this compound as modifier shows a good electrocatalytic activity toward the oxidation of ascorbic acid(AA). CCDC: 707968. |
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| Keywords: | hydrothermal synthesis piperazine electrochemical properties |
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