Peculiarities of the Porous Structure of Aluminosilicate Mesoporous Substances Obtained in The Presence of Biotemplates |
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Authors: | Smelaya Z V Matkovskaya L A Goltsov Yu G |
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Institution: | (1) L. V. Pisarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Prospekt Nauki, 03039 Kyiv, Ukraine |
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Abstract: | Supramolecular structures of lecithin occurred to be the template in the synthesis of mesoporous aluminosilicates; using of various combinations of lecithin and cetyltrimethyl-ammonium bromide or octadecylamine as templating agents allowed to obtain mesoporous substances with pores up to 100 Å, as well as biporous materials in aluminosilicate system. In the presence of glucose oxidase and cetyltrimethyl-ammonium bromide combinations aluminosilicate substances with complex porous structure were shown to be formed (pore size distributions exhibited 3 peaks, corresponding 3 effective size of mesopores in the 30–100 Å range). The investigation of sorption of glucose oxidase on obtained aluminosilicate mesoporous substances was carried out, the results obtained allowus to consider such materials as prospect for creation high capable and selective sorbents for biomolecules sorption, as well as active elements of chemical and biosensors. |
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Keywords: | biomimetic chemistry biomineralization glucose oxidase Kelvin equation lecithin mesoporous aluminosilicates methanol ad(de)sorption isotherm porous structure |
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