Spin transition charted in a fluorophore-tagged thermochromic dinuclear iron(II) complex |
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| Authors: | Garcia Yann Robert François Naik Anil D Zhou Guangyuan Tinant Bernard Robeyns Koen Michotte Sébastien Piraux Luc |
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| Affiliation: | Institute of Condensed Matter and Nanosciences, Université Catholique de Louvain, Place Louis Pasteur 1, 1348 Louvain-la-Neuve, Belgium. yann.garcia@uclouvain.be |
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| Abstract: | The first crystal structures of a dinuclear iron(II) complex with three N1,N2-1,2,4-triazole bridges in the high-spin and low-spin states are reported. Its sharp spin transition, which was probed using X-ray, calorimetric, magnetic, and (57)Fe Mossbauer analyses, is also delineated in the crystalline state by variable-temperature fluorimetry for the first time. |
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