Imido-bridged homo- and heterobimetallic complexes |
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Authors: | Lorber Christian Vendier Laure |
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Institution: | Laboratoire de Chimie de Coordination (LCC), Centre National de la Recherche Scientifique (CNRS), 205 route de Narbonne, F-31077 Toulouse, France. lorber@lcc-toulouse.fr |
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Abstract: | Transamination reactions of primary amines with group 4 and 5 amido precursors M(NMe(2))(4) have been studied to prepare homo- and heterobimetallic complexes (Me(2)N)(2)M(1)(μ-NR(1))(μ-NR(2))M(2)(NMe(2))(2)(NHMe(2))(x)] (x = 0, 1) with two identical or distinct bridging imido ligands. |
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