| 简便合成二酰基二硒醚 |
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| 引用本文： | 赵华绒,余浩杰,吴兆彬.简便合成二酰基二硒醚[J].有机化学,2005,25(7):862-864. |
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| 作者姓名： | 赵华绒 余浩杰 吴兆彬 |
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| 作者单位： | 浙江大学化学系,杭州,310027 |
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| 基金项目： | 浙江省分析测试基金，浙江省教育厅资助项目 |
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| 摘 要： | 芳基硒代酰胺与酰氯以1∶1的摩尔比在氯仿溶液中作用, 可以较高的产率得到二酰基二硒醚, 而芳基硒代酰胺与酰氯以1∶2的摩尔比反应时则生成二酰基硒醚. 提出了反应可能的机理.
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| 关 键 词： | 芳基硒代酰胺 合成 酰氯 二酰基二硒醚 |
| 收稿时间： | 2004-11-10 |
| 修稿时间： | 2005-1-24 |
A Convenient Synthesis of Diacyl Diselenides |
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| Zhao Hua-rong,YU Hao-Jie,WU Zhao-Bin.A Convenient Synthesis of Diacyl Diselenides[J].Chinese Journal of Organic Chemistry,2005,25(7):862-864. |
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| Authors: | Zhao Hua-rong YU Hao-Jie WU Zhao-Bin |
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| Institution: | (Department of Chemistry, Zhejiang University, Hangzhou 310027) |
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| Abstract: | Diacyl diselenides were synthesized by the reaction of arylselenoamides with acyl chlorides at 1∶1 molar ratio using chloroform as solvent in good yields. Diacyl selenides were formed by the reaction of arylselenoamides with acyl chlorides at 1∶2 molar ratio. A mechanism for the new method of generating diacyl diselenides and diacyl selenides was proposed. |
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| Keywords: | arylselenoamide synthesis acyl chloride diacyl diselenide |
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