Metal complex electrocatalytic reduction of 1,1-dihalocyclopropanes |
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| Authors: | Yanilkin V V Strunskaya E I Nastapova N V Iaksimyuk N I Bredikhina Z A Sharafutdinova D R Bredikhin A A |
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| Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088 Kazan, Russian Federation |
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| Abstract: | Catalytic electroreduction of several substituted gem-dihalocyclopropanes was studied in the presence of metal salen-complexes by polarography, cyclic voltammetry, and preparative electrolysis. Monohalocyclopropanes (54—59%) and the corresponding allene (5—9%) were the main reduction products. The reaction rate constants were determined. The inner-sphere electron transfer was shown to occur under these conditions. |
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| Keywords: | halocyclopropanes allene electrochemistry catalysis salen-complexes kinetics |
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