| 交替马来酸酐共聚物多缩乙二醇酯盐络合物中阳离子－高分子相互作用的研究 |
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| 引用本文： | 丁黎明,林云青,周子南. 交替马来酸酐共聚物多缩乙二醇酯盐络合物中阳离子－高分子相互作用的研究[J]. 高分子学报, 1995, 0(3): 360-364 |
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| 作者姓名： | 丁黎明 林云青 周子南 |
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| 作者单位： | 中国科学院长春应用化学研究所 130022 |
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| 摘 要： |
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| 关 键 词： | SPE 离子传输 马来酸酐 共聚物 多缩乙二醇脂 |
| 收稿时间： | 1993-11-10 |
STUDY ON THE CATION-POLYMER INTERACTION OF POLYMER ELECTROLYTES BASED ON AN ALTERNATING MALEIC ANHYDRIDE COPOLYMER WITH OLIGO-OXYETHLENE SIDE CHAINS |
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| DING Li-ming,LIN Yun-qing,ZHOU Zi-nan. STUDY ON THE CATION-POLYMER INTERACTION OF POLYMER ELECTROLYTES BASED ON AN ALTERNATING MALEIC ANHYDRIDE COPOLYMER WITH OLIGO-OXYETHLENE SIDE CHAINS[J]. Acta Polymerica Sinica, 1995, 0(3): 360-364 |
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| Authors: | DING Li-ming LIN Yun-qing ZHOU Zi-nan |
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| Affiliation: | Changchun Institute of Applied Chemistry; Academia Sinica; Changchun 130022 |
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| Abstract: | A study of the complexes of BM350 with four different alkali metal salts: LIClO4, NaClO4, LiBF4 and LiCF3SO3 by mid-IR and XPS is presented. The results of mid-IR shows that the coordination of canon to polymer makes the C-O-C band become broader and shift slightly. XPS analysis shows that the O atom of two situations can coordinate to Li+(or Na+) and also that this coordination results in the reduction of the electron orbit binding energy of Cl, F and S. |
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