BINEPINES: chiral binaphthalene-core monophosphepine ligands for multipurpose asymmetric catalysis |
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Authors: | Gladiali Serafino Alberico Elisabetta Junge Kathrin Beller Matthias |
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Affiliation: | Dipartimento di Chimica, Università di Sassari, via Vienna 2, 07100 Sassari, Italy. gladiali@uniss.it |
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Abstract: | The atropisomeric structure of 4,5-dihydro-3H-dinaphtho[2,1-c;1',2'-e]phosphepine is the common axially chiral scaffold of a library of monophosphine ligands nicknamed BINEPINES that have shown a quite remarkable stereoselection efficiency in a broad variety of enantioselective reactions involving the formation of new C-H or C-C or C-X bonds. In this critical review the properties and scope of this type of chiral ligands are illustrated (70 references). |
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