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Influence of the Type of a Ligand on the Intensity of Luminescence of Ln3+ Ions in Aqueous Solutions
Authors:I. V. Barsukov  E. N. Kabaeva  V. V. Syt'ko  S. D. Umreiko
Affiliation:(1) F. Skorina Gomel' State University, 104 Sovetskaya Str., Gomel', 246699, Belarus;(2) Belarusian State University, Minsk, Belarus
Abstract:The luminescence characteristics of hydrated Ln3+ ions and their complexes with some acidic ligands have been investigated. The possibility of determining the stability of the complexes of lanthanides in solutions from the intensity of luminescence bands is shown. The influence of the characteristic features of the f-electron shell of Ln3+ on the formation of the spectrochemical series is discussed.
Keywords:luminescence  complexing  three-valent ions of lanthanides  acidic ligands  aqueous solutions
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