A missing allene of heavy Group 14 elements: 2-germadisilaallene |
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Authors: | Iwamoto Takeaki Abe Takashi Kabuto Chizuko Kira Mitsuo |
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Affiliation: | Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan. |
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Abstract: | The first stable 2-germadisilaallene was synthesized by the reduction of a 2 ratio 1 mixture of a stable dialkylsilylene and dichlorogermylene-dioxane complex with KC8; the 2-germadisilaallene showed dynamic disorder similar to the corresponding trisilaallene in the solid state. |
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