The first rhodaboratrane: [RhCl(PPh3){B(mt)3}](Rh-->B)(mt = methimazolyl) |
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| Authors: | Crossley Ian R Foreman Mark R St-J Hill Anthony F White Andrew J P Williams David J |
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| Institution: | Research School of Chemistry, Institute of Advanced Studies, Australian National University, Canberra, ACT Australia. |
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| Abstract: | The reaction of Rh(C6H5)Cl2(PPh3)2] with NaHB(mt)3](mt = methimazolyl) provides RhCl(PPh3){B(mt)3}](Rh-->B) the first authentic example of a compound with a rhodium-boron dative bond. |
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