| 1-烃基-1-硅杂环丁烷的合成及其Si—H键伸缩振动频率与结构关系的研究 |
| |
| 引用本文： | 于凯,朴生勋,周秀中. 1-烃基-1-硅杂环丁烷的合成及其Si—H键伸缩振动频率与结构关系的研究[J]. 高等学校化学学报, 1991, 0(3) |
| |
| 作者姓名： | 于凯 朴生勋 周秀中 |
| |
| 作者单位： | 延边大学化学系，延边大学化学系，南开大学化学系 133002，133002 |
| |
| 摘 要： | 硅杂环丁烷在有机硅化学中是一类非常重要的小分子环系化合物。由于硅杂环丁烷和环丁烷的环张力相似,因而显示出较高的反应活性。例如能与某些试剂作用,生成开环产物;在光解或热解条件下,产生具有Si=C结构的高活性中间体,可用以合成多种有机硅化合物。
|
| 关 键 词： | 1-烃基-1-硅杂环丁烷 合成 Si-H键 伸缩振动频率 一元线性回归分析 |
Synthesis of 1-Hydrocarbyl-1-Silacyclobutane and Studies on the Relationship Between the Si-H Stretching Vibration and Molecular Structure |
| |
| Yu Kai,Piao Sheng-xun. Synthesis of 1-Hydrocarbyl-1-Silacyclobutane and Studies on the Relationship Between the Si-H Stretching Vibration and Molecular Structure[J]. Chemical Research In Chinese Universities, 1991, 0(3) |
| |
| Authors: | Yu Kai Piao Sheng-xun |
| |
| Abstract: | The 1-hydrocarbyl-1-Silacyclobutanes. HRSiCH2CH2CH2 (R=H, Me, Et, i-Pr, Cyclo-hexyl, CH2Ph, Ph, p-MeC6H.4, p-ClC6H4, w-MeC6H4 m-ClCH4, Mesityl) were synthesized by the reaction of 1, 1-dichloro- 1-silacyclobutane with LiAlH.,. The structure of 9 new compounds were characterized by 'H NMR, 1R and MS. The relationship between the Si-H stretching vibration and the electronic and steric effects of substituents on the atom Si was discussed. |
| |
| Keywords: | 1-hydrocarbyl-l-silacyclobutane. Synthesis Si-H bond Stretching vibration frequency Monadic linear regression analysis |
| 本文献已被 CNKI 等数据库收录！ |
|
