Single-stage plasma-arc synthesis of metallo-endofullerences |
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Authors: | V I Gerasimov G V Kalinin Yu A Nikonov Yu F Titovets A E Kalabushkin O S Alekhin K V Nekrasov S N Rusetskaya O V Arapov N I Alekseev E V Kustova V V Lishchuk M A Pleshkov K N Semenov V A Keskinov N A Charykov |
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Institution: | (1) Innovation at Leningrad Institutes and Enterprises, Private Company, St. Petersburg, Russia;(2) Ioffe Physicotechnical Institute, Russian Academy of Sciences, St. Petersburg, Russia;(3) St. Petersburg State University, St. Petersburg, Russia;(4) St. Petersburg State Institute of Technology (Technical University), St. Petersburg, Russia |
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Abstract: | Single-stage plasma-arc synthesis of metallo-endofullerences of the types C60Pd, C60Ni, and C60Cr, whose content in a mixture of extracted fullerenes was 0.05 to 0.15 wt %, was performed. The effect of introduction of these metals into the reaction plasma on the total yield of fullerenes and on the fraction composition of the fullerene mixture was studied. The fullerene mixtures were analyzed by mass spectrometry and liquid chromatography. |
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