| New Chiral N,S-Ligands with Thiophenyl at Benzylic Position. Palladium(II)-catalyzed Enantioselective Allylic Alkylation |
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| 引用本文： | 吴昊,巫循伟,侯雪龙,戴立信,王全瑞. New Chiral N,S-Ligands with Thiophenyl at Benzylic Position. Palladium(II)-catalyzed Enantioselective Allylic Alkylation[J]. 中国化学, 2002, 0(9) |
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| 作者姓名： | 吴昊 巫循伟 侯雪龙 戴立信 王全瑞 |
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| 作者单位： | WU，Hao a WU，Xun Wei b HOU，Xue Long ，b，c DAI，Li Xin b WANG，Quan Rui a aDepartment of Chemistry，Fudan University，Shanghai 200433，China |
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| 基金项目： | theNationalNaturalScienceFoundationofChina (No .2 0 132 0 10 )，theMajorStateBasicResearchDevelopmentProgram (No.G2 0 0 0 0 775 0 6 )，theNationalOutstandingYouthFund ChineseAcademyofSciences，theShanghaiCommitteeofSci enceandTechnology |
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| 摘 要： | Ｃｈｉｒａｌｌｉｇａｎｄｓｐｌａｙａｃｒｕｃｉａｌｒｏｌｅｉｎａｓｙｍｍｅｔｒｉｃｃａｔａｌｙｓｉｓ .Ｔｏｄａｔｅａｖａｒｉｅｔｙｏｆｌｉｇａｎｄｓｈａｖｅｂｅｅｎｓｙｎｔｈｅ ｓｉｚｅｄａｎｄｐｒｏｖｅｄｔｏｂｅｅｆｆｅｃｔｉｖｅ .Ａｍｏｎｇｔｈｅｍｔｈｅｌｉｇａｎｄｓ1ｗｉｔｈｂｏｔｈｃｏｏｒｄｉｎａｔｅａｔｏｍｓａｔｂｅｎｚｅｎｅｒｉｎｇ ｐｏｓｉｔｉｏｎｓｓｈｏｗｇｏｏｄｔｏｅｘｃｅｌｌｅｎｔａｓｙｍｍｅｔｒｉｃｉｎｄｕｃｔｉｏｎｉｎｃａｔａｌｙｔｉｃａｓｙｍｍｅｔｒｉｃｒｅａｃｔｉｏｎｓ …
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New Chiral N,S-Ligands with Thiophenyl at Benzylic Position. Palladium(II)-catalyzed Enantioselective Allylic Alkylation |
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| Abstract: | bState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China cShanghai Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China New chiral N,S ligands with oxazoline and thiophenyl substituents at benzene ring and benzylic position have been prepared and applied in palladium catalyzed asymmetric allylic alkylation reaction to provide the product with high yield and entantioselectivity ( 82%-93% ee ). |
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| Keywords: | N S ligands palladium catalyst asymmetric allylic alkylation |
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