| Iron(Ⅱ) hydrides bearing a tetradentate PSNP ligand |
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| 引用本文： | Jianguo Liu,Ailing Zhang,Heng Song,Qingxiao Tong,Chen-Ho Tung,Wenguang Wang. Iron(Ⅱ) hydrides bearing a tetradentate PSNP ligand[J]. 中国化学快报, 2018, 29(6): 949-953. DOI: 10.1016/j.cclet.2017.09.059 |
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| 作者姓名： | Jianguo Liu Ailing Zhang Heng Song Qingxiao Tong Chen-Ho Tung Wenguang Wang |
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| 作者单位： | a School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China;b Department of Chemistry, Shantou University, Shantou 515063, China |
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| 基金项目： | We gratefully acknowledge financial support from the "1000 Youth Talents Plan", the National Natural Science Foundation of China (Nos. 21402107, 91427303), and the Natural Science Foundation of Shandong Province (Nos. ZR2014M011). |
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| 摘 要： | Iron(II) hydrides bearing PSNP tetradentate ligand were synthesized and well characterized. The hydrido iron complex [2H(NCMe)](BF4) is an extremely efficient catalyst for the hydroboration of aldehydes at room temperature.
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| 收稿时间： | 2017-08-06 |
Iron(II) hydrides bearing a tetradentate PSNP ligand |
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| Jianguo Liu,Ailing Zhang,Heng Song,Qingxiao Tong,Chen-Ho Tung,Wenguang Wang. Iron(II) hydrides bearing a tetradentate PSNP ligand[J]. Chinese Chemical Letters, 2018, 29(6): 949-953. DOI: 10.1016/j.cclet.2017.09.059 |
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| Authors: | Jianguo Liu Ailing Zhang Heng Song Qingxiao Tong Chen-Ho Tung Wenguang Wang |
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| Affiliation: | a School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China;b Department of Chemistry, Shantou University, Shantou 515063, China |
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| Abstract: | A new class of iron(II) hydrides based on a tetradentate PSNP ligand were synthesized and fully characterized. All the iron(II) complexes feature a folded PSNP ligand with cis reactive sites. The hydrido iron complex [2H(NCMe)](BF4) is capable of catalyzing aldehyde hydroboration by pinacolborane (HBpin) and with extremely high efficiency at room temperature. Aldehydes with various functional groups are compatible. |
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| Keywords: | Iron(II) hydride Iron catalysis Tetradentate ligand Hydroboration Aldehydes |
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