An experimental study of exit pressures for polymer melts |
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Authors: | T. W. Chan B. Pan H. Yuan |
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Affiliation: | (1) Polymer Science Department, Beijing Institute of Chemical Technology, 100013 Beijing, China |
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Abstract: | A slit die apparatus is used to measure exit pressures for five different polymer melts. Viscosity data obtained from the same apparatus agree well with values obtained from a cone-and-plate rheometer or a capillary rheometer. Except for a PVC sample where thermal degradation was found to occur, the exit pressures obtained by linear extrapolation of the measured pressure profiles are all positive, and increase with increasing shear stress. The values of the first normal stress difference calculated according to the exit pressure theory are of the right order of magnitude and in some cases correlate satisfactorily with values measured in a cone-and-plate rheometer. However, the high sensitivity of the exit pressure values to the method of extrapolation and the wild scatter of exit pressure data for some materials make it difficult to use the exit pressure method as a routine procedure for accurate determination of the first normal stress difference. |
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Keywords: | Exitpressure first normalstress difference viscosity polymermelts slitdie |
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