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Direct orthoruthenation of planar prochiral pyridine derivatives by C-H bond activation with [Ru(CO)2Cl2]n and its unexpected stereoselectivity
Authors:Hijazi Akram  Djukic Jean-Pierre  Pfeffer Michel  Ricard Louis  Kyritsakas-Gruber Nathalie  Raya Jesus  Bertani Philippe  de Cian André
Institution:Institut de Chimie de Strasbourg, CNRS LC3 UMR 7177, Université Louis Pasteur, 67000 Strasbourg, France.
Abstract:The treatment of planar prochiral pyridine derivatives with d6 Ru(CO)2Cl2]n stereoselectively and efficiently produces new dimeric ortho-ruthenated complexes.
Keywords:
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