Vicarious Nucleophilic Substitution of Hydrogen and Formation of Aziridine Rings in Reactions of Benzonaphthyridines and their N-Oxides with Chloromethyl Phenyl Sulfone |
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Authors: | Barbara Bachowska Teresa Zujewska |
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Affiliation: | (1) Institute of Chemistry, Pedagogical University, PL-42201 Częstochowa, Poland, PL |
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Abstract: | Summary. Treatment of benzonaphthyridines with chloromethyl phenyl sulfone in the presence of base led to the formation of aziridine rings annelated to the benzonaphthyridine skeleton, whereas their N-oxides underwent vicarious nucleophilic substitution of hydrogen (VNS), thus leading to the corresponding phenylsulfonylmethyl derivatives. Received December 11, 2000. Accepted (revised) January 22, 2001 |
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Keywords: | . Benzonaphthyridine N-oxides Vicarious nucleophilic substitution (VNS) Annulation α -Halo carbanions. |
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