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反应气压对直流磁控反应溅射制备的氧化银薄膜的结构和光学性质的影响
引用本文:张增院,郜小勇,冯红亮,马姣民,卢景霄.反应气压对直流磁控反应溅射制备的氧化银薄膜的结构和光学性质的影响[J].物理学报,2011,60(1):16110-016110.
作者姓名:张增院  郜小勇  冯红亮  马姣民  卢景霄
作者单位:郑州大学物理工程学院材料物理教育部重点实验室,郑州 450052
基金项目:国家自然科学基金(批准号:60807001)和河南省教育厅自然科学研究计划项目(批准号:2010A140017)资助的课题.
摘    要:利用直流磁控反应溅射技术,通过调节反应气压(RP),在250 ℃衬底温度下制备了一系列氧化银 (AgxO) 薄膜,并利用X射线衍射谱、能量色散谱和分光光度计重点研究了RP对AgxO薄膜的结构和光学性质的影响. 研究结果表明,随着RP从0.5 Pa升高到3.5 Pa,薄膜明显呈现了从两相(AgO+Ag2O)到单相(Ag2O)结构再到两相(Ag2O+AgO)结构的演变. 特 关键词: 氧化银薄膜 直流磁控反应溅射 X射线衍射谱 光学性质

关 键 词:氧化银薄膜  直流磁控反应溅射  X射线衍射谱  光学性质
收稿时间:2010-03-13

Effect of the reactive pressure on the structure and optical properties of silver oxide films deposited by direct-current reactive magnetron sputtering
Zhang Zeng-Yuan,Gao Xiao-Yong,Feng Hong-Liang,Ma Jiao-Min,Lu Jing-Xiao.Effect of the reactive pressure on the structure and optical properties of silver oxide films deposited by direct-current reactive magnetron sputtering[J].Acta Physica Sinica,2011,60(1):16110-016110.
Authors:Zhang Zeng-Yuan  Gao Xiao-Yong  Feng Hong-Liang  Ma Jiao-Min  Lu Jing-Xiao
Institution:Key Laboratory of Materials Physics of Ministry of Education, School of Physics and Engineering, Zhengzhou University, Zhengzhou 450052, China;Key Laboratory of Materials Physics of Ministry of Education, School of Physics and Engineering, Zhengzhou University, Zhengzhou 450052, China;Key Laboratory of Materials Physics of Ministry of Education, School of Physics and Engineering, Zhengzhou University, Zhengzhou 450052, China;Key Laboratory of Materials Physics of Ministry of Education, School of Physics and Engineering, Zhengzhou University, Zhengzhou 450052, China;Key Laboratory of Materials Physics of Ministry of Education, School of Physics and Engineering, Zhengzhou University, Zhengzhou 450052, China
Abstract:Using direct-current reactive magnetron sputtering technique, a series of silver oxide (AgxO) films were deposited at a substrate temperature of 250 ℃ by modifying the reactive pressure (RP). Effect of the RP on the film structure and optical properties was investigated by X-ray diffractometry, energy dispersive spectroscopy and spectrophotometry. An evolution of the phase structure from biphased (AgO+Ag2O) to single-phased (Ag2O), and then to biphased (Ag2O+AgO) occurred with the RP increasing from 0.5 to 3.5 Pa for the AgxO films. Single-phase Ag2O film, specially, was deposited at RP=2.5 Pa, which was capable of lowering the threshold of thermal decomposition temperature of the AgxO film. The film transmissivity in transparent region increased with the RP increasing, while the film reflectivity and absorptivity decreased with the RP increasing. This result is attributed to the evolution of the phase structure and the decrease of the film thickness. The absorption edge of the biphased (AgO+Ag2O) AgxO film was located near 2.75 eV, whereas the absorption edge of the single-phase (Ag2O) and Ag2O-dominated biphased (Ag2O+AgO) AgxO film was located near 2.5 eV.
Keywords:silver oxide film  direct-current reactive magnetron sputtering  X-ray diffraction spectra  optical properties
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