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Extraction of Uranium(VI) by N-Octanoylpiperidine in Toluene
Authors:Shao Hua  Han Jing-Tian  Sun Guo-Xin  Bao Bo-Rong  Sun Si-Xiu
Institution:(1) Shanghai Institute of Nuclear Research, The Chinese Academy of Sciences, P.O. Box 800-204, Shanghai, 201800, P.R. China;(2) School of Chemistry, Shandong University, Ji'nan, 250100, P.R. China
Abstract:The extraction of uranium(VI) from nitric acid by N-octanoylpiperidine (OPPD) in toluene has been investigated at varying concentrations of nitric acid, extractant, salting-out agent LiNO3 and at different temperatures. The mechanism of extraction is discussed in the light of the results obtained. The extracted species have also been investigated using FT-IR spectrometry. The related thermodynamic functions were calculated.
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