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| Cu2(μ-dppb)2(μ-Cl)2的合成、晶体结构及非线性光学性质 | |
| 引用本文： | 景苏,殷陶,王玉晓,宋瑛林,李一志,郑和根,忻新泉. Cu2(μ-dppb)2(μ-Cl)2的合成、晶体结构及非线性光学性质[J]. 无机化学学报, 2002, 18(11): 1169-1172 |
| 作者姓名： | 景苏 殷陶 王玉晓 宋瑛林 李一志 郑和根 忻新泉 |
| 作者单位： | 1. 南京大学配位化学研究所,配位化学国家重点实验室,南京,210093;南京工业大学理学院应化系,南京,210009 2. 南京大学配位化学研究所,配位化学国家重点实验室,南京,210093 3. 哈尔滨工业大学应用物理系,哈尔滨,150001 |
| 基金项目： | 国家自然科学基金资助项目(No.20171020)，国家自然科学基金重大项目(No.90101028)。 |
| 摘 要： | The complex Cu2(μ-dppb)2(μ-Cl)2 has been synthesized from the reaction of CuCl， dppb and (n-Bu)4NCl. The crystal belongs to the triclinic with space group P1. The unit cell parameters are: a=9.939(4)?， b=10.083(6)?， c=14.104(5)?， α=76.46(3)°， β=71.02(2)°， γ=70.87(5)°. The single crystal X-ray diffraction analysis reveals that it has a bi-ring structure with a symmetry center at the middle of two Copper atoms. The outer ring is a 14-membered ring of Cu-dppb-Cu-dppb， and the inner ring is a 4-membered ring composed of two Cl- and two Cu(Ⅰ). Investigation of third-order optical nonlinearity shows that it exhibits considerable nonlinear absorptive and self-defocusing effect with α2=1.75×10-13m·W-1 and n2=3.19×10-18m2·W-1. CCDC: 193113. |
| 关 键 词： | 铜(Ⅰ)配合物 dppb 晶体结构 非线性光学性质 |
| 修稿时间： | 2002-08-24 |
Synthesis, Crystal Structure and Optical Nonlinearity Study of Cu2 (μ-dppb) 2 (μ- Cl) 2 |
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| JING Su,YIN Tao,WANG Yu-Xiao,SONG Yin-Lin,LI Yi-Zhi,ZHENG He-Gen and XIN Xin-Quan. Synthesis, Crystal Structure and Optical Nonlinearity Study of Cu2 (μ-dppb) 2 (μ- Cl) 2[J]. Chinese Journal of Inorganic Chemistry, 2002, 18(11): 1169-1172 | |
| Authors: | JING Su YIN Tao WANG Yu-Xiao SONG Yin-Lin LI Yi-Zhi ZHENG He-Gen XIN Xin-Quan |
| Abstract: | |
| Keywords: | copper? complex dppb crystal structure optical nonlinearity |
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