Synthesis of a distanna [2]ferrocenophane and reactivity of [2]ferrocenophanes towards elemental sulfur and selenium |
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| Authors: | H. Bera A. Oechsner F. Seeler R. Sigritz |
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| Affiliation: | Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany |
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| Abstract: | Here we report the synthesis and crystal structure of a new [2]ferrocenophane [Fe(η5-C5H4)2(SntBu2)2] with a sterically demanding distannanediyl bridge. The reactivity of the title compound towards selected main group elements was examined and in addition, this reactivity pattern was established for the related diboranediyl bridged [2]ferrocenophane [Fe(η5-C5H4)2(BNMe2)2]. |
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| Keywords: | Boron Iron Tin Sulfur Selenium ansa-Complexes |
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