An efficient and recyclable water-soluble cyclopalladated complex for aqueous Suzuki reactions under aerial conditions |
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Authors: | Jin Zhou Xiaoyan Li |
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Affiliation: | a School of Chemistry and Chemical Engineering, Shandong University, Shanda Nanlu 27, 250100 Jinan, People’s Republic of China b School of Chemical Engineering, Shandong University of Technology, Zibo 255049, China |
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Abstract: | Several water-soluble cyclopalladated complexes with five- or six-membered rings have been prepared as air-stable solids from Schiff base ligands bearing an N-phenyl sulfonate groups. Cyclopalladated complexes with six-membered rings show high catalytic efficiency for the Suzuki reactions of aryl bromides with phenylboronic acid in aqueous solvents under mild conditions. Palladium complex 1 can be used for five reaction cycles in high conversions for the Suzuki reactions in neat water without additives. The catalytic process for the Suzuki couplings is proved by TEM analysis to proceed on Pd(0) nanoparticles. Surfactant-protected palladium nanoparticles present lower activities and poorer recyclability for the coupling reactions than those generated in situ without additives. |
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Keywords: | Cyclopalladated complex Palladium Suzuki reaction Water soluble Aqueous |
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