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A new tris(ferrocenylamine) ditertiary phosphine: Synthesis and co-ordination studies

Authors:	Mark RJ Elsegood George W Weaver

Institution:	Department of Chemistry, Loughborough University, Loughborough, Leics LE11 3TU, UK

Abstract:	The new tris(ferrocenylamine) ditertiary phosphine 1,1′-{FcCH₂N(CH₂PPh₂)CH₂(η⁵-C₅H₄)}₂Fe Fc = (η⁵-C₅H₅)Fe(η⁵-C₅H₄)] has been prepared along with two coordination complexes. All compounds have been characterised by a combination of spectroscopic and analytical methods. The single crystal X-ray structure of the pentametallic Ru₂Fe₃ complex 5 has been determined.

Keywords:	Phosphine ligands Ferrocenyl compounds Organometallic complexes X-ray crystallography Electrochemical studies
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