Carbon-nitrogen bond activation of amines by rhodium(III) porphyrin complexes |
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| Authors: | Ching Chi Au |
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| Affiliation: | Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, People’s Republic of China |
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| Abstract: | Carbon-nitrogen bond activation of amines by rhodium porphyrin chloride has been achieved to give rhodium porphyrin alkyl complexes. Rhodium porphyrin hydride and rhodium porphyrin dimer were proposed as the intermediates in cleaving the C-N bond. |
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| Keywords: | Carbon-nitrogen bond activation |
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