Addition of difluoromethyl radicals to glycals: a new route to alpha-CF2-D-glycosides |
| |
| Authors: | Moreno Benjamin Quehen Cindy Rose-Hélène Maureen Leclerc Eric Quirion Jean-Charles |
| |
| Institution: | Laboratoire d'Hétérochimie Organique, UMR 6014 CNRS, IRCOF, INSA et Université de Rouen, 1 rue Tesnière, 76821 Mont Saint-Aignan Cedex, France. |
| |
| Abstract: | The synthesis of synthetically useful alpha-CF2-glycosides by radical addition of ethyl bromodifluoroacetate onto 2-benzyloxyglycals is described. The methodology provides an access to alpha-O-glycoside mimics and, potentially, to valuable alpha-O-glycoconjugate analogues. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
