The 1-6 weberite Na2Te2O7 and some observations on compounds with the weberite structure |
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Authors: | Osvald Knop Gérard Demazeau |
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Affiliation: | Department of Chemistry, Dalhousie University, Halifax, Nova Scotia B3H 4J3, Canada;Laboratoire de Chimie du Solide du CNRS, Université de Bordeaux I, 33405 Talence Cedex, France |
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Abstract: | The 1-6 weberite Na2Te2O7 (Imm2, a = 7.233 Å, b = 10.104 Å, c = 7.454 Å) has been prepared by high-pressure synthesis. It is shown that ) (the mean unit-cell dimension per formula unit) of oxide weberites A2B2O7 can be represented as a linear function of the effective ionic radii of A and B. The problem of the true space-group symmetry of weberite is discussed. |
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Keywords: | To whom correspondence may be addressed. |
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