Conformational locking for band gap control in 3,4-propylenedioxythiophene based electrochromic polymers |
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| Authors: | Walczak Ryan M Cowart John S Abboud Khalil A Reynolds John R |
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| Institution: | George and Josephine Butler Polymer Research Laboratory, Department of Chemistry, Center for Macromolecular Sciences and Engineering, University of Florida, Gainesville, Florida 32611, USA. |
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| Abstract: | We report a tethered poly(3,4-propylenedioxythiophene) derivative with a built-in polymer conformation restriction which locks the conjugated chain at a specific dihedral angle, thus providing a handle in which to tune the optical and electronic properties of the material. |
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