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New glycosidic and other constituents from hulls of <Emphasis Type="Italic">Oryza sativa</Emphasis>
Authors:I M Chung  H Y Park  S C Chun  J J Kim  A Ahmad
Institution:(1) College of Life and Environmental Sciences, Konkuk University, Seoul, 143-701, South Korea
Abstract:Three new compounds, 4-hydroxymethylene-7-(9,9,13-trimethylcyclohexyl)-heptanyl-3′,7′,7′-trimethylcyclohexa-2′,4′-dien-1′-oate (1), 1-(n-hexadec-7-enoxy)-6-(n-octadecanoxy)-β-D-glucopyranoside (2), and (Z)-12-hydroxy-9-octadecenoic acid-12-β-D-glucopyranoside (3), along with the known compound hexacosanoic acid (4), were isolated and identified from the rice hulls of Oryza sativa. Their structures were elucidated by 1D and 2D NMR spectroscopic techniques (1H-1H COSY, 1H-13C HETCOR, DEPT) aided by EIMS, FABMS, HRFABMS, and IR spectra. Published in Khimiya Prirodnykh Soedinenii, No. 4, pp. 344–347, July–August, 2007.
Keywords:Oryza sativa L  rice hull composition  4-hydroxymethylene-7-(9  9  13-trimethylcyclohexyl)-heptanyl-3′    7′    7−  trimethylcyclohexa-2′    4′  -dien-1′  -oate  1-(n-hexadec-7-enoxy)-6-(n-octadecanoxy)-β  -D-glucopyranoside  (Z)-12-hydroxy-9-octadecenoic acid-12-β  -D-glucopyranoside
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