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Synthesis and characterization of difluoromethylene-homo[60]fullerene, C60(CF2) |
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| Authors: | Pimenova Anna S Kozlov Andrey A Goryunkov Alexey A Markov Vitaliy Yu Khavrel Pavel A Avdoshenko Stanislav M Ioffe Ilya N Sakharov Sergey G Troyanov Sergey I Sidorov Lev N |
| Affiliation: | Chemistry Department, Moscow State University, Moscow 119992, Russia. |
| Abstract: | Refluxing of the o-DCB solution of C60 with CF2ClCOONa and 18-crown-6 leads to formation of C60(CF2)n (n = 1-3); the monoadduct C60(CF2) has been found to consist of the main [6,6]- and minor [5,6]-isomers, both having an open structure. |
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