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Reaction of glycidyl phenyl ether with imines: A model study of latent hardeners of epoxy resins in the presence of water
Authors:Kentarou Suzuki  Nobuki Matsu‐Ura  Hisakazu Horii  Yuko Sugita  Fumio Sanda  Takeshi Endo
Abstract:The hydrolyses of several imines and their reactions with glycidyl phenyl ether were examined under highly humid conditions as a model study for the development of water‐initiated hardeners for epoxy resins. Diethyl ketone‐based imines were hydrolyzed more efficiently than methyl isobutyl ketone‐based imines. The reactions of glycidyl phenyl ether with the imines depended on their hydrolysis rates and the basicity of the amines generated from them. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 971–975, 2002
Keywords:diethyl ketone  imines  water‐initiated latent hardener  one‐component epoxy resins  adhesives  coatings
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