Di‐μ‐chloro‐bis({2‐[N,N‐bis(2‐aminoethyl)amino‐κ3N]ethylaminium}copper(II)) bis(naphthalene‐1,5‐disulfonate) pentahydrate |
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Authors: | Cai‐Hong Chen Jiwen Cai Xiao‐Ming Chen |
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Abstract: | The title compound, Cu2(C6H19N4)2Cl2](C10H6O6S2)2·5H2O, is comprised of discrete Cu2(tren)2Cl2]2+ dimers {tren is 2‐N,N‐bis(2‐aminoethyl)amino]ethylaminium} and naphthalene‐1,5‐disulfonate anions. Two Cl? anions bridge two CuII ions, each of which is also coordinated by two of the primary and the tertiary amino N atoms of the tren ligand, giving each metal atom a distorted square‐pyramidal coordination geometry. The cation lies about an inversion centre and the asymmetric unit also has two independent anions lying about inversion centres. |
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