Kinetic features of thermal decomposition of cobalt acetylacetonate and development of catalysts for the oxidation of carbon monoxide,based on the decomposition products |
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Authors: | E I Tsyganova I I Didenkulova V M Shekunova V I Faerman Yu A Aleksandrov |
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Institution: | (1) Research Institute of Chemistry, Lobachevsky Nizhni Novgorod State University, Nizhni Novgorod, Russia |
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Abstract: | The kinetic features of thermal decomposition of cobalt acetylacetonate in a vacuum were elucidated, and the volatile thermolysis products were identified. The homogeneous-heterogeneous character of the process was shown. Catalysts for the oxidation of CO to CO2 were developed on the basis of cobalt acetylacetonate decomposition products and synthetic cellular ceramics, and the kinetic and activation parameters of the oxidation were determined.Translated from Zhurnal Obshchei Khimii, Vol. 74, No. 11, 2004, pp. 1770–1774.Original Russian Text Copyright © 2004 by Tsyganova, Didenkulova, Shekunova, Faerman, Aleksandrov.This revised version was published online in April 2005 with a corrected cover date. |
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