Activation and transformation of white phosphorus by palladium(<Emphasis Type="SmallCaps">ii</Emphasis>) complexes |
| |
| Authors: | R M Kagirov A V Voloshin I Kh Rizvanov O G Sinyashin D G Yakhvarov |
| |
| Institution: | 1.A. E. Arbuzov Institute of Organic and Physical Chemistry,Kazan Research Center of the Russian Academy of Sciences,Kazan,Russian Federation;2.Kazan State University,Kazan,Russian Federation |
| |
| Abstract: | A reaction of bis(triphenylphosphine)palladium dibromide with white phosphorus in the presence of NaBPh4 selectively gives phosphorous acid H3PO3. The mechanism of the formation involves coordination of a white phosphorus molecule, ligand exchange, and hydrolysis of
the coordinated P4 molecule in the coordination sphere of palladium. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
