| An Efficient Deselenenylation Reaction to the Synthesis of 3, 5-Disubstituted Isoxazoline and Isoxazole |
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| 作者姓名： | Wei Ming XU Yu Guang WANG Zhen Hua CHEN Xian HUANG |
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| 作者单位： | [1]Department of Chemistry, Zhejiang University （Xixi Campus）, Hangzhou 310028 |
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| 摘 要： | The development of organoselenium chemistry1 has been expanding rapidly during the last decades. Among them, organic selenides are key intermediates, for that they can be efficiently introduced, manipulated, and removed through selenoxide syn-elimination2. Our research group3 has been interested in the application of selenium in organic synthesis for several years. Isoxazolinyl substituted phenyl selenide 13a, although a β-H exists in the molecule, did not undergo selenoxide syn-elimination e…
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| 关 键 词： | 3-甲基-5-异唑 合成方法 反应率 有机化学 |
| 收稿时间： | 2004-10-10 |
An Efficient Deselenenylation Reaction to the Synthesis of 3, 5-Disubstituted Isoxazoline and Isoxazole |
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| Wei Ming XU Yu Guang WANG Zhen Hua CHEN Xian HUANG.An Efficient Deselenenylation Reaction to the Synthesis of 3, 5-Disubstituted Isoxazoline and Isoxazole[J].Chinese Chemical Letters,2005,16(8):995-996. |
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| Authors: | Wei;Ming;XU;Yu;Guang;WANG;Zhen;Hua;CHEN;Xian;HUANG |
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| Institution: | Xixi Campus |
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| Abstract: | A mild deselenenylation reaction protocol for the preparation of 3, 5-disubstituted isoxazolines and their further application to 3-methyl-5-substituted isoxazoles both in solution phase and solid phase was reported. |
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| Keywords: | Deselenenylation reaction isoxazoline isoxazole |
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