Synthesis and crystal structure of diferrocenylmethoxyethylamine |
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Authors: | Haibo Zhang Baoguo Li Ruijue Hu Zhanxi Bian Shuzhen Bai |
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Affiliation: | (1) College of Chemistry and Chemical Engineering, Inner Mongolia University, Huhhot, 010021, People's Republic of China |
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Abstract: | The reaction of diethanolamine with diferrocenylmethyl carbonium (2) that was generated by diferrocenylmethanol (1) treated with BF3 in CH2Cl2 provided the synthesis of title compound diferrocenylmethoxyethylamine (3). The structure of 3 was determined by the X-ray diffraction (XRD) with crystal data: monoclinic P21/n space group and a=5.8419(14) Å, b=13.572(3) Å, c=23.839(6) Å, α=90°, β=91.827(5)°, γ=90°, V=1889.2(8) Å3, Z=4, D c =1.558 mg·m?3, μ=1.548 mm?1, F(000)=920. The intra- and inter-molecular H bonding modes in 3 were demonstrated both in molecular crystal structure and IR spectral characterization. |
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Keywords: | Diferrocenylmethoxyethylamine Diferrocenylmethyl carbonium Diethanolamine Crystal structure |
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