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Electrochromism of octaalkoxymethyl-substituted lutetium diphthalocyanine
Institution:1. Institute of Chemistry, The Hebrew University of Jerusalem, Jerusalem, 91904, Israel;2. Centre for Theoretical and Computational Chemistry, Department of Chemistry, University of Oslo, 1033 Blindern, N-0315, Oslo, Norway;1. Laboratory of Radiochemistry, Department of Chemistry, University of Helsinki, P.O. Box 55, FI-00014, Finland;2. Geological Survey of Finland, Espoo, Finland;3. Department of Chemistry Loughborough University, Leics., UK;4. The Finnish Radiation and Nuclear Safety Authority, Finland;1. Department of Health Sciences, Faculty of Medical Sciences, Kyushu University, Japan;2. Department of Health Sciences, Graduate School of Medical Sciences, Kyushu University, Japan;1. Department of Mechanical and Production Engineering Niigata University, 8050, Ikarashi 2-no-cho, Niigata 950-2181, Japan;2. Graduate School of Science and Technology Niigata University, 8050, Ikarashi 2-no-cho, Niigata 950-2181, Japan
Abstract:The electrochromic properties of bis(octaalkoxymethylphthalocyaninato)lutetium films were studied by voltammetry and visible spectrometry. The green molecular films can be oxidized reversibly to form an orange cation and reduced to form a blue anion. The potential of the oxidation step depends on the anion of the aqueous electrolyte in contact with the film.
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