Direction of alkylation of 5-aryl-1,3,4-oxadiazoline-2-thiones |
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Authors: | A. A. Ziyaev G. G. Galust'yan |
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Abstract: | The reaction of potassium salt of 5-(2,4-dichlorophenyl)-1,3,4-oxadiazoline-2-thione with dimethyl sulfate was carried out in water and HMPT. It was shown that the nature of the solvent affects the ratio of the formed products of S- and N-methylation. The alkylation of 5-aryl-1,3,4-oxadiazoline-2-thiones with isomeric butyl chlorides showed that the reaction takes place only with n-butyl chloride with the formation of the corresponding S-butyl-substituted derivative.Institute of the Chemistry of Vegetable Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent 700170. Translated from Khimiya Geterotsikliheskikh Soedinenii, No. 9, pp. 1268–1270, September, 1997. |
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