General synthesis of pyrroloquinolizidines: synthesis of an unnatural homologue of the pyrroloindolizidine myrmicarin alkaloid 215B |
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| Authors: | Angle Steven R Qian Xuelei Lily Pletnev Alexandre A Chinn Jason |
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| Affiliation: | Department of Chemistry, University of California-Riverside, Riverside, California 92521-0403, USA. steven.angle@wright.edu |
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| Abstract: | A general synthesis approach to pyrroloquinolizidines (3,4,5,5a,6,7,8-heptahydropyrrolo[2,1,5-de]quinolizines) via a münchnone 1,3-dipolar cycloaddition is reported. The approach was applied to the synthesis of an unnatural pyrroloquinolizidine homologue of myrmicarin 215B. |
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