| 多氟烷氧基取代金属酞菁配合物的简便合成及其光谱特征 |
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| 引用本文： | 司玉贵,龚跃法,张正波.多氟烷氧基取代金属酞菁配合物的简便合成及其光谱特征[J].高等学校化学学报,1999,20(3):403-406. |
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| 作者姓名： | 司玉贵 龚跃法 张正波 |
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| 作者单位： | 华中理工大学化学系, 武汉 430074 |
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| 摘 要： | 制备了一些氯酞菁金属配合物,研究了它们与多氟醇盐的反应.结果表明,该反应可以方便地在氯酞菁环上引入多氟烷氧基.借此合成了一些多氟烷氧基取代金属酞菁配合物.产物经分离提纯后,用元素分析、IR、UV-Vis及19FNMR谱进行了表征,并观测了多氟烷氧基的引入对其脂溶性、热稳定性及电子光谱性质的影响.
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| 关 键 词： | 多氟金属酞菁配合物 合成 脂溶性 热力学稳定性 |
| 收稿时间： | 1998-06-08 |
Synthesis and Spectroscopic CharactErizations of Polyfluoroalkoxy Chlorophthalocyanines |
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| SI Yu-Gui,GONG Yue-Fa,ZHANG Zheng-Bo.Synthesis and Spectroscopic CharactErizations of Polyfluoroalkoxy Chlorophthalocyanines[J].Chemical Research In Chinese Universities,1999,20(3):403-406. |
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| Authors: | SI Yu-Gui GONG Yue-Fa ZHANG Zheng-Bo |
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| Institution: | Department of Chemistry, Huazhong University of Science and Technology, Wuhan, 430074 |
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| Abstract: | The preparation of some chlorophthalocyanines and the reactions of them with sodium polyfluoroalkoxide were reported in this paper. Some polyfluoroalkoxy chlorophthalocyanines have been obtained by this way, and characterized by elementary analysis, IR, UVVis, 19F NMR spectra after purification. The effects of introduction of polyfluoroalkoxy group in the ring on the solubility, thermodynamic stability and electronic spectra were also discussed. |
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| Keywords: | Polyfluoroalkoxy chlorophthalocyanine Synthesis Liposolubility Thermodynamic stability |
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