| FeCl3与30% H2O2对醇的催化氧化 |
| |
| 引用本文： | 达玉霞,杨志旺,雷自强.FeCl3与30% H2O2对醇的催化氧化[J].西北师范大学学报,2006,42(5):72-75. |
| |
| 作者姓名： | 达玉霞 杨志旺 雷自强 |
| |
| 作者单位： | 甘肃省高分子材料重点实验室西北师范大学化学化工学院 甘肃兰州730070 |
| |
| 摘 要： | 以FeCl3为催化剂,环境友好的30%H2O2为氧化剂,研究了对甲氧基苯甲醇的催化氧化,考察了影响反应的各种因素,实现了最优条件下其他醇的催化氧化.结果表明,用30%H2O2氧化醇时,FeCl3是较好的催化剂,在温和条件下,一系列醇都可被氧化成相应的羰基化合物.
|
| 关 键 词： | 醇 催化氧化 30％ H2O2 |
| 文章编号： | 1001-988X（2006）05-0072-04 |
| 收稿时间： | 2006-05-08 |
| 修稿时间： | 2006-06-22 |
Catalytic oxidation of alcohols using FeCl3 and 30% H2O2 |
| |
| DA Yu-xia,YANG Zhi-wang,LEI Zi-qiang.Catalytic oxidation of alcohols using FeCl3 and 30% H2O2[J].Journal of Northwest Normal University Natural Science (Bimonthly),2006,42(5):72-75. |
| |
| Authors: | DA Yu-xia YANG Zhi-wang LEI Zi-qiang |
| |
| Institution: | Gansu Key Laboratory of Polymer Materials, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, Gansu, China |
| |
| Abstract: | p-Methoxybenzalcohol is oxidized by 30% H_2O_2 with the catalysis of FeCl_3 under mild condition.The oxidation reaction is well investigated,and the reaction condition is optimized.Other alcohols are also oxidized with high conversion and product selectivity under the optimizing condition.The results indicate that FeCl_3 is a promising catalyst for the oxidation of alcohol with 30% H_2O_2 as oxidant. |
| |
| Keywords: | FeCl3 |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
