|
|||||
|
|
Nitration equilibrium in the meso-erythritol-aqueous nitric acid system |
|
| Authors: | A. I. Kazakov G. V. Lagodzinskaya N. G. Yunda L. P. Andrienko A. M. Korolev Yu. I. Rubtsov G. B. Manelis L. T. Eremenko |
| Affiliation: | (1) N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka |
| Abstract: | Twelve equilibrium constants have been measured from 16 for sequential-parallel reactions in meso-erythritol nitration to the fully nitrated compound in aqueous HNO3. Free-energy changes during nitration of the aliphatic polyatomic alcohols, glycerol and meso-erythritol, are highest when diprimary dinitrates (NOON) and (NON) are produced.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2248–2253, October, 1991. |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ | |